Metal ion complexation by a new, highly sterically hindered, bowl-shaped carboxylate ligand
Ferman A. Chavez, Lawrence Que, William B. Tolman
Abstract
Ferman A. Chavez, Lawrence Que, William B. Tolman
Abstract
A carboxylate encapsulated by arene groups arranged in a bowl-like shape coordinates to Fe(II), Co(II) and Cu(II) to form mononuclear complexes with atypical structures enforced by the extreme steric demands of the ligand.
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A carboxylate encapsulated by arene groups arranged in a bowl-like shape coordinates to Fe(II), Co(II) and Cu(II) to form mononuclear complexes with atypical structures enforced by the extreme steric demands of the ligand.
Key concepts: Steric effects, Carboxylate, Ligand (biochemistry), Chemistry, Metal, Ion, Metal ions in aqueous solution, Crystallography