2001Chemical CommunicationsRequires access

Metal ion complexation by a new, highly sterically hindered, bowl-shaped carboxylate ligand

Ferman A. Chavez, Lawrence Que, William B. Tolman

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Abstract

A carboxylate encapsulated by arene groups arranged in a bowl-like shape coordinates to Fe(II), Co(II) and Cu(II) to form mononuclear complexes with atypical structures enforced by the extreme steric demands of the ligand.

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A carboxylate encapsulated by arene groups arranged in a bowl-like shape coordinates to Fe(II), Co(II) and Cu(II) to form mononuclear complexes with atypical structures enforced by the extreme steric demands of the ligand.

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Available abstract

A carboxylate encapsulated by arene groups arranged in a bowl-like shape coordinates to Fe(II), Co(II) and Cu(II) to form mononuclear complexes with atypical structures enforced by the extreme steric demands of the ligand.

Key concepts: Steric effects, Carboxylate, Ligand (biochemistry), Chemistry, Metal, Ion, Metal ions in aqueous solution, Crystallography

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