1999•Chemistry LettersRequires access

Fractionation of Boron Isotopes to Bis(2-hydroxyalkyl)amine Borate and Boric Acid in Aqueous Solutions

Takahiro Hirotsu, Takaaki Sonoda, Yoji Makita, Hirofumi Kanoh, Takagi Norio, Kenta Ooi, Manabu Senō

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Abstract

Abstract 10B is more fractionated to B(OH)L {H2L: a ligand having a bis(2-hydroxyalkyl)amino group (alkyl: ethyl and propyl)} with a tetrahedral coordination mode than to B(OH)3 with a planar triangular coordination mode in aqueous solutions, exhibiting an isotope separation factor of 1.027 at 25 °C, which is greater than the upper limit of anion exchangers.

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Abstract 10B is more fractionated to B(OH)L {H2L: a ligand having a bis(2-hydroxyalkyl)amino group (alkyl: ethyl and propyl)} with a tetrahedral coordination mode than to B(OH)3 with a planar triangular coordination mode in aqueous solutions, exhibiting an isotope separation factor of 1.027 at 25 °C, which is greater than the upper limit of anion exchangers.

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Available abstract

Abstract 10B is more fractionated to B(OH)L {H2L: a ligand having a bis(2-hydroxyalkyl)amino group (alkyl: ethyl and propyl)} with a tetrahedral coordination mode than to B(OH)3 with a planar triangular coordination mode in aqueous solutions, exhibiting an isotope separation factor of 1.027 at 25 °C, which is greater than the upper limit of anion exchangers.

Key concepts: Chemistry, Boric acid, Boron, Isotopes of boron, Aqueous solution, Amine gas treating, Inorganic chemistry, Fractionation

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