Fractionation of Boron Isotopes to Bis(2-hydroxyalkyl)amine Borate and Boric Acid in Aqueous Solutions
Takahiro Hirotsu, Takaaki Sonoda, Yoji Makita, Hirofumi Kanoh, Takagi Norio, Kenta Ooi, Manabu Senō
Abstract
Takahiro Hirotsu, Takaaki Sonoda, Yoji Makita, Hirofumi Kanoh, Takagi Norio, Kenta Ooi, Manabu Senō
Abstract
Abstract 10B is more fractionated to B(OH)L {H2L: a ligand having a bis(2-hydroxyalkyl)amino group (alkyl: ethyl and propyl)} with a tetrahedral coordination mode than to B(OH)3 with a planar triangular coordination mode in aqueous solutions, exhibiting an isotope separation factor of 1.027 at 25 °C, which is greater than the upper limit of anion exchangers.
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Abstract 10B is more fractionated to B(OH)L {H2L: a ligand having a bis(2-hydroxyalkyl)amino group (alkyl: ethyl and propyl)} with a tetrahedral coordination mode than to B(OH)3 with a planar triangular coordination mode in aqueous solutions, exhibiting an isotope separation factor of 1.027 at 25 °C, which is greater than the upper limit of anion exchangers.
Key concepts: Chemistry, Boric acid, Boron, Isotopes of boron, Aqueous solution, Amine gas treating, Inorganic chemistry, Fractionation