1995•Synthesis and Reactivity in Inorganic and Metal-Organic ChemistryRequires access

Some Coordination Complexes of Dichlorobis (Cyclopentadienyl)-Titanium (IV) and Dichlorobis (Cyclopentadienyl) Zirconium(IV) With N2S2and S2O2Ligands

Anuj Mittal, Archana Shukla, P. R. Shukla, Ashish K. Pathak, Nihal Ahmad

Abstract

Some new distorted trigonal bipyramidal complexes of dichlorobis (cyclopentadienyl) titanium (IV) and dichlorobis-(cyclopentadienyl) zirconium(IV) with N2S2 and S2O2 ligands derived from o-aminobenzenethiol have synthesised. A number of cyclisation reactions and addition reactions have been carried out on the complexes in order to study their effect on the stability of carbon-metal-carbon bonding and on metal ligand bonding behaviour. The compounds were characterized by elemental analysis, conductance measurement, IR spectral and 1H NMR spectral studies.

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Key concepts: Cyclopentadienyl complex, Zirconium, Titanium, Chemistry, Inorganic chemistry, Organic chemistry, Catalysis