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2014•Russian Journal of Applied ChemistryRequires access

Low-temperature reversible addition-fragmentation chain transfer (RAFT) polymerization of methyl methacrylate

Egor Polozov, С. Д. Зайцев, Yu. D. Semchikov

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Abstract

Controlled/living radical polymerization of methyl methacrylate under the conditions of reversible addition-fragmentation chain transfer was performed. The reaction occurs at high rates, with the control over molecular-weight characteristics of poly(methyl methacrylate) preserved. The polymeric reversible chain-transfer agent exhibits high performance in polymerization of methyl methacrylate and in its block copolymerization with styrene.

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What this paper is about

Controlled/living radical polymerization of methyl methacrylate under the conditions of reversible addition-fragmentation chain transfer was performed. The reaction occurs at high rates, with the control over molecular-weight characteristics of poly(methyl methacrylate) preserved. The polymeric reversible chain-transfer agent exhibits high performance in polymerization of methyl methacrylate and in its block copolymerization with styrene.

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Available abstract

Controlled/living radical polymerization of methyl methacrylate under the conditions of reversible addition-fragmentation chain transfer was performed. The reaction occurs at high rates, with the control over molecular-weight characteristics of poly(methyl methacrylate) preserved. The polymeric reversible chain-transfer agent exhibits high performance in polymerization of methyl methacrylate and in its block copolymerization with styrene.

Key concepts: Chain transfer, Chemistry, Reversible addition−fragmentation chain-transfer polymerization, Raft, Polymer chemistry, Copolymer, Methyl methacrylate, Living polymerization

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