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1993•Synthesis and Reactivity in Inorganic and Metal-Organic ChemistryRequires access

Group IV Metal Complexes of the Dithiocarbamate Ligahd Derived from Propanediamine

K. S. Siddiqi, Fathi Aqra, Syed Asad Ali Shah, S. A. A. Zaidi

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Abstract

Fropanediamine dithiocarbamate and its metal complexes with MCl4. (Si = M Ge, Sn, Ti, and Zr) and Ph2-SnCl2 have been synthesized and characterized. The results indicate that MCI4. reacts in a 1, 4 (metal : dithiocarbamate) ratio yielding an octahedral compound with two symmetrically and two unsym-metrically bound dithiocarbamato groups while Ph2SnCl2 reacts in a 1: 1 ratio leading to the formation of a stable five-coordinate complex with the phenyl groups occupying the equatorial positions.

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Fropanediamine dithiocarbamate and its metal complexes with MCl4. (Si = M Ge, Sn, Ti, and Zr) and Ph2-SnCl2 have been synthesized and characterized. The results indicate that MCI4. reacts in a 1, 4 (metal : dithiocarbamate) ratio yielding an octahedral compound with two symmetrically and two unsym-metrically bound dithiocarbamato groups while Ph2SnCl2 reacts in a 1: 1 ratio leading to the formation of a stable five-coordinate complex with the phenyl groups occupying the equatorial positions.

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Available abstract

Fropanediamine dithiocarbamate and its metal complexes with MCl4. (Si = M Ge, Sn, Ti, and Zr) and Ph2-SnCl2 have been synthesized and characterized. The results indicate that MCI4. reacts in a 1, 4 (metal : dithiocarbamate) ratio yielding an octahedral compound with two symmetrically and two unsym-metrically bound dithiocarbamato groups while Ph2SnCl2 reacts in a 1: 1 ratio leading to the formation of a stable five-coordinate complex with the phenyl groups occupying the equatorial positions.

Key concepts: Dithiocarbamate, Metal, Group (periodic table), Chemistry, Organic chemistry

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