2001•Angewandte Chemie International EditionRequires access
Ligand-Controlled Chemoselectivity in the Classical Oxidative Addition Reactions of MeI and Aldehydes to Rhodium(I) Complexes
Roman Goikhman, David Milstein
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Abstract
The strikingly different reactivity of similar complexes of the type [PnRhX] is strongly dependent on the number and nature of the trialkylphosphane (P) and of the anionic ligand (X), and can be selectively directed to the oxidative addition of either aldehydes or MeI [Eqs. (1) and (2)].