Synthesis of Chlorotris(triphenylphoshine)rhodium(I) fromtrans-Chlorocarbonylbis (triphenylphosphine)rhodium(I)
Richard W. Fries, JOHN K. STILLE
Abstract
Richard W. Fries, JOHN K. STILLE
Abstract
Chlorotris(triphenylphosphine)rhodium(I), 1, was prepared in 73.4% yield by the treatment of trans-chlorocarbonylbis (triphenylphosphine)-rhodium(I), 2, with α-chlorotoluene followed by treatment with triphenylphosphine in refluxing ethanol.
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Chlorotris(triphenylphosphine)rhodium(I), 1, was prepared in 73.4% yield by the treatment of trans-chlorocarbonylbis (triphenylphosphine)-rhodium(I), 2, with α-chlorotoluene followed by treatment with triphenylphosphine in refluxing ethanol.
Key concepts: Triphenylphosphine, Rhodium, Chemistry, Ethanol, Yield (engineering), Medicinal chemistry, Organic chemistry, Materials science