1981•The Journal of Chemical PhysicsRequires access
Infrared matrix isolation studies on the t-butyl radical
J. Pacansky, J. S. Chang
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Abstract
The infrared spectrum of the t-butyl radical isolated in an argon matrix was obtained by gas phase pyrolysis of azoisobutane and 2-nitrosoisobutane. The infrared spectrum is consistent with a C3v structure for the radical. The data obtained from the matrix isolation studies were used to reassess the ΔH°f,300 for the radical.