2012Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal ChemistryRequires access

A Novel 3D Mn(II) Supramolecular Coordination Polymer Constructed by 1,10-Phenanthroline Derivative and Flexible Dicarboxylate

Jiku Wang, Hao Chen, Feifei Liu, Wei Li

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Abstract

A new Mn(II) coordination polymers based on the 1,10- phenanthroline derivative and flexible dicarboxylate, namely [Mn2(L)2(trans-1,4-chdc)] (1), where L = 11-fluoro-dipyrido[3,2-a: 2′,3′-c]phenazine and trans-1,4-chdc = 1,4-cyclohexanedicar- boxylate, has been successfully synthesized under hydrothermal condition. Compound 1 shows a one-dimensional chain structure. The neighboring chains are extended into a 3D supramolecular architecture by π-π interactions. Its thermal property was also investigated.

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A new Mn(II) coordination polymers based on the 1,10- phenanthroline derivative and flexible dicarboxylate, namely [Mn2(L)2(trans-1,4-chdc)] (1), where L = 11-fluoro-dipyrido[3,2-a: 2′,3′-c]phenazine and trans-1,4-chdc = 1,4-cyclohexanedicar- boxylate, has been successfully synthesized under hydrothermal condition. Compound 1 shows a one-dimensional chain structure. The neighboring chains are extended into a 3D supramolecular architecture by π-π interactions. Its thermal property was also investigated.

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Available abstract

A new Mn(II) coordination polymers based on the 1,10- phenanthroline derivative and flexible dicarboxylate, namely [Mn2(L)2(trans-1,4-chdc)] (1), where L = 11-fluoro-dipyrido[3,2-a: 2′,3′-c]phenazine and trans-1,4-chdc = 1,4-cyclohexanedicar- boxylate, has been successfully synthesized under hydrothermal condition. Compound 1 shows a one-dimensional chain structure. The neighboring chains are extended into a 3D supramolecular architecture by π-π interactions. Its thermal property was also investigated.

Key concepts: Phenanthroline, Supramolecular chemistry, Derivative (finance), Coordination polymer, Phenazine, Hydrothermal circulation, Hydrothermal synthesis, Crystallography

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