1979•Journal of the Chemical Society Perkin Transactions 2Requires access

Linear solvation energy relationships. Part 1. Solvent polarity–polarizability effects on infrared spectra

Mortimer J. Kamlet, Robert W. Taft

Abstract

The linear solvation energy relationship (LSER) concept is shown to apply to i.r. spectra. Solvatochromic shifts of a variety of X = O, C–Cl, and O–H ⋯ B stretching frequencies and solvent effects on absorption intensities are linear with solvent π*-values. Values of s in the solvatochromic equation, ν=ν0+sπ*, are related to chromophore structures.

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Key concepts: Solvatochromism, Solvation, Polarizability, Chromophore, Chemistry, Polarity (international relations), Solvent polarity, Solvent