Evidence for the characterisation of the C–H···π interaction as a weak hydrogen bond: toluene and chlorobenzene solvates of 2,3,7,8-tetraphenyl-1,9,10-anthyridine
N. Madhavi, Gautam R. Desiraju, Amy K. Katz, H. L. Carrell, Ashwini Nangia
Abstract
N. Madhavi, Gautam R. Desiraju, Amy K. Katz, H. L. Carrell, Ashwini Nangia
Abstract
The crystal structures of the toluene and chlorobenzene solvates of 2,3,7,8-tetraphenyl-1,9,10-anthyridine are nearly identical save for differences in the mode of solvent inclusion; these differences have an important bearing on the nature of the C–H···π interactions in these structures.
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The crystal structures of the toluene and chlorobenzene solvates of 2,3,7,8-tetraphenyl-1,9,10-anthyridine are nearly identical save for differences in the mode of solvent inclusion; these differences have an important bearing on the nature of the C–H···π interactions in these structures.
Key concepts: Chlorobenzene, Toluene, Hydrogen bond, Solvent, Chemistry, Crystal structure, Crystal (programming language), Inclusion (mineral)