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Asymmetric Deprotonation with Alkyllithium–(−)‐Sparteine

Dieter Hoppe, Guido Christoph

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Abstract

Abstract Introduction Non‐Mesomerically Stabilized Organolithium Compounds (−)‐Sparteine‐Induced Lithiation with Formation of Benzyl‐Type Organolithiums Allyllithium–(−)‐Sparteine Complexes Lithium–(−)‐Sparteine Complexes of 2‐Alkynyl Carbamates Axial–Chiral and Planar–Chiral Lithium–(−)‐Sparteine Complexes Enantioselective Addition of Achiral Carbanionic Compounds in the Presence of (−)‐Sparteine

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Abstract Introduction Non‐Mesomerically Stabilized Organolithium Compounds (−)‐Sparteine‐Induced Lithiation with Formation of Benzyl‐Type Organolithiums Allyllithium–(−)‐Sparteine Complexes Lithium–(−)‐Sparteine Complexes of 2‐Alkynyl Carbamates Axial–Chiral and Planar–Chiral Lithium–(−)‐Sparteine Complexes Enantioselective Addition of Achiral Carbanionic Compounds in the Presence of (−)‐Sparteine

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Available abstract

Abstract Introduction Non‐Mesomerically Stabilized Organolithium Compounds (−)‐Sparteine‐Induced Lithiation with Formation of Benzyl‐Type Organolithiums Allyllithium–(−)‐Sparteine Complexes Lithium–(−)‐Sparteine Complexes of 2‐Alkynyl Carbamates Axial–Chiral and Planar–Chiral Lithium–(−)‐Sparteine Complexes Enantioselective Addition of Achiral Carbanionic Compounds in the Presence of (−)‐Sparteine

Key concepts: Sparteine, Lithium (medication), Deprotonation, Organolithium compounds, Enantioselective synthesis, Chemistry, Stereochemistry, Organic chemistry

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