1964•Journal of the American Oil Chemists SocietyRequires access

Analog computers and kinetics of hydrogenation

Royden O. Butterfield, E. Duane Bitner, Charles R. Scholfield, Herbert J. Dutton

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Abstract

Abstract Investigations of the kinetics of consecutive reactions frequently require complicated calculations to determine specific reaction rate constants from experimental data. Analog computers permit a convenient empirical adjustment of rate constants in kinetic equations to match experimental results. Once an electronic network analogous to the chemical reaction system is set up, specific reaction rates can be determined by adjusting potentiometers, which are the analogs of the rate constants, until an acceptable fit of calculated and experimental data is reached. Applicability of a small analog computer to the kinetics of hydrogenation is presented.

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Abstract Investigations of the kinetics of consecutive reactions frequently require complicated calculations to determine specific reaction rate constants from experimental data. Analog computers permit a convenient empirical adjustment of rate constants in kinetic equations to match experimental results. Once an electronic network analogous to the chemical reaction system is set up, specific reaction rates can be determined by adjusting potentiometers, which are the analogs of the rate constants, until an acceptable fit of calculated and experimental data is reached. Applicability of a small analog computer to the kinetics of hydrogenation is presented.

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Available abstract

Abstract Investigations of the kinetics of consecutive reactions frequently require complicated calculations to determine specific reaction rate constants from experimental data. Analog computers permit a convenient empirical adjustment of rate constants in kinetic equations to match experimental results. Once an electronic network analogous to the chemical reaction system is set up, specific reaction rates can be determined by adjusting potentiometers, which are the analogs of the rate constants, until an acceptable fit of calculated and experimental data is reached. Applicability of a small analog computer to the kinetics of hydrogenation is presented.

Key concepts: Kinetics, Reaction rate constant, Rate equation, Chemical kinetics, Set (abstract data type), Reaction rate, Thermodynamics, Kinetic energy

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