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1960•Canadian Journal of ChemistryOpen access

THE ENERGY OF HYDROGEN BONDING IN THE SYSTEM: ACETONE–CHLOROFORM

A. N. Campbell, E. M. Kartzmark

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Abstract

It is shown that(1) acetone and chloroform form a compound stable in the solid state;(2) acetone and carbon tetrachloride do not form a compound;(3) the enthalpies of mixing of acetone and chloroform and of acetone and carbon tetrachloride have been determined;(4) from these figures the energy of hydrogen bonding in the acetone–chloroform system is evaluated as 2.7 kcal ± 0.1.

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It is shown that(1) acetone and chloroform form a compound stable in the solid state;(2) acetone and carbon tetrachloride do not form a compound;(3) the enthalpies of mixing of acetone and chloroform and of acetone and carbon tetrachloride have been determined;(4) from these figures the energy of hydrogen bonding in the acetone–chloroform system is evaluated as 2.7 kcal ± 0.1.

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Available abstract

It is shown that(1) acetone and chloroform form a compound stable in the solid state;(2) acetone and carbon tetrachloride do not form a compound;(3) the enthalpies of mixing of acetone and chloroform and of acetone and carbon tetrachloride have been determined;(4) from these figures the energy of hydrogen bonding in the acetone–chloroform system is evaluated as 2.7 kcal ± 0.1.

Key concepts: Chloroform, Acetone, Chemistry, Carbon tetrachloride, Hydrogen bond, Hydrogen, Inorganic chemistry, Organic chemistry

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