1967•Journal of The Electrochemical SocietyRequires access

Low-Pressure Oxidation of Zirconium

Jeremy A. Levitan, Joseph E. Draley, C. J. Van Drunen

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Abstract

Low‐pressure oxidation of zirconium at high temperatures exhibited a pressure dependence, and several stages of oxidation could be distinguished: an initial period was followed by two periods with a linear rate dependence. Transition from the first linear period to the following linear period was accompanied by increase in oxidation rate. Surface reaction control is suggested for these periods. Linear oxidation was followed by a period when the rate was limited by a protective oxide film.

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Low‐pressure oxidation of zirconium at high temperatures exhibited a pressure dependence, and several stages of oxidation could be distinguished: an initial period was followed by two periods with a linear rate dependence. Transition from the first linear period to the following linear period was accompanied by increase in oxidation rate. Surface reaction control is suggested for these periods. Linear oxidation was followed by a period when the rate was limited by a protective oxide film.

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Available abstract

Low‐pressure oxidation of zirconium at high temperatures exhibited a pressure dependence, and several stages of oxidation could be distinguished: an initial period was followed by two periods with a linear rate dependence. Transition from the first linear period to the following linear period was accompanied by increase in oxidation rate. Surface reaction control is suggested for these periods. Linear oxidation was followed by a period when the rate was limited by a protective oxide film.

Key concepts: Zirconium, Period (music), Oxide, Linear relationship, Redox, Reaction rate, Induction period, Materials science

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