Numerical Study of Nonequilibrium Diagram Theory

In this paper we numerically analyze the first few diagrams in a Boltzmann-like collision operator that occurs in Severne's exact kinetic equation for the singlet distribution function. A similar analysis was used by Allen and Cole in deriving their singlet and doublet kinetic equations. Our analysis shows that the diagrams neglected by Allen and Cole in their kinetic equations are not negligible and these should be incorporated into dense fluid theories. The Allen–Cole kinetic transport coefficients and equilibrium pair correlation function are presented and calculated for dense argon. These results are not promising.