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2014•Russian Journal of Physical Chemistry BRequires access

Catalytic nitrobenzene hydrogenation in supercritical carbon dioxide

Valentin Yu. Doluda, A. Yu. Tereshchenkov, Galina N. Demidenko, N. Lakina, Mikhail G. Sulman, Mikhail G. Sulman, Valentina G. Matveeva

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Abstract

The results of catalytic hydrogenation of nitrobenzene on Pd-containing catalysts in different media, such as supercritical carbon dioxide (SC-CO 2 ) and isopropyl alcohol, as well as without any solvent are presented. A significant increase in the reaction rate of nitrobenzene hydrogenation was observed in SC-CO 2 . The catalytic activity decreased with decreasing metal content in the catalyst.

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What this paper is about

The results of catalytic hydrogenation of nitrobenzene on Pd-containing catalysts in different media, such as supercritical carbon dioxide (SC-CO 2 ) and isopropyl alcohol, as well as without any solvent are presented. A significant increase in the reaction rate of nitrobenzene hydrogenation was observed in SC-CO 2 . The catalytic activity decreased with decreasing metal content in the catalyst.

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Available abstract

The results of catalytic hydrogenation of nitrobenzene on Pd-containing catalysts in different media, such as supercritical carbon dioxide (SC-CO 2 ) and isopropyl alcohol, as well as without any solvent are presented. A significant increase in the reaction rate of nitrobenzene hydrogenation was observed in SC-CO 2 . The catalytic activity decreased with decreasing metal content in the catalyst.

Key concepts: Nitrobenzene, Catalysis, Isopropyl alcohol, Supercritical carbon dioxide, Chemistry, Supercritical fluid, Carbon dioxide, Solvent

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