Hexamethylenetetramine-Mediated Transesterification of β-Keto Esters
Lúcia C. S. Aguiar, Rodrigo Gaspar Ribeiro, Rodrigo O. M. A. de Souza, Mário Luiz Araújo de Almeida Vasconcellos, Bianca Oliveira, Leonardo Ferreira
Abstract
Lúcia C. S. Aguiar, Rodrigo Gaspar Ribeiro, Rodrigo O. M. A. de Souza, Mário Luiz Araújo de Almeida Vasconcellos, Bianca Oliveira, Leonardo Ferreira
Abstract
Treatment of methyl or ethyl β-keto esters with primary, secondary, or tertiary alcohols in the presence of a catalytic amount of hexamethylenetetramine results in good to high yields of the corresponding esters.
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Treatment of methyl or ethyl β-keto esters with primary, secondary, or tertiary alcohols in the presence of a catalytic amount of hexamethylenetetramine results in good to high yields of the corresponding esters.
Key concepts: Hexamethylenetetramine, Chemistry, Transesterification, Organic chemistry, Primary (astronomy), Catalysis, Tertiary alcohols, Primary alcohol