A novel glycosyl donor for chemo-enzymatic oligosaccharide synthesis: 4,6-dimethoxy-1,3,5-triazin-2-yl glycoside
Tomonari Tanaka, Masato Noguchi, Atsushi Kobayashi, Shin‐ichiro Shoda
Abstract
Tomonari Tanaka, Masato Noguchi, Atsushi Kobayashi, Shin‐ichiro Shoda
Abstract
A novel activated glycosidic compound, 4,6-dimethoxy-1,3,5-triazin-2-yl beta-lactoside (DMT-beta-Lac), which can be prepared directly from lactose in water without using any protecting groups, was found to be an efficient glycosyl donor for enzymatic glycosylation catalyzed by an endo-1,4-beta-glucanase.
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A novel activated glycosidic compound, 4,6-dimethoxy-1,3,5-triazin-2-yl beta-lactoside (DMT-beta-Lac), which can be prepared directly from lactose in water without using any protecting groups, was found to be an efficient glycosyl donor for enzymatic glycosylation catalyzed by an endo-1,4-beta-glucanase.
Key concepts: Glycosidic bond, Glycosyl, Glycosylation, Chemistry, Glycoside, Lactose, Glycoside hydrolase, Glycosyl donor