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2011•Chemical CommunicationsRequires access

Selective oxidation of methanol to dimethoxymethane over bifunctional VOx/TS-1 catalysts

Shuang Chen, Shengping Wang, Xinbin Ma, Jinlong Gong

Open publisher page 68 citations

Abstract

This communication describes the design of bifunctional VO(x)/TS-1 catalysts with enhanced redox and acidic character via doping SO(4)(2-) and PO(4)(3-) for selective oxidation of methanol to dimethoxymethane. Redox sites enable the production of formaldehyde, while acidic sites favor the condensation of formaldehyde to DMM.

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What this paper is about

This communication describes the design of bifunctional VO(x)/TS-1 catalysts with enhanced redox and acidic character via doping SO(4)(2-) and PO(4)(3-) for selective oxidation of methanol to dimethoxymethane. Redox sites enable the production of formaldehyde, while acidic sites favor the condensation of formaldehyde to DMM.

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OpenAlex reports 68 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

This communication describes the design of bifunctional VO(x)/TS-1 catalysts with enhanced redox and acidic character via doping SO(4)(2-) and PO(4)(3-) for selective oxidation of methanol to dimethoxymethane. Redox sites enable the production of formaldehyde, while acidic sites favor the condensation of formaldehyde to DMM.

Key concepts: Dimethoxymethane, Bifunctional, Formaldehyde, Catalysis, Methanol, Chemistry, Redox, Condensation

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