2006•Russian Journal of General ChemistryRequires access

Preparation and spectroscopic and electrochemical properties of complexes of dibenzo-and dipyrido-substituted 1,4-diazines

O. A. Farus, К. П. Балашев, А. В. Иванов, T. A. Tkacheva, A. G. Panova

Abstract

The spectroscopic and electrochemical properties of palladium ethylenediamine complexes [Pd(N^N)En]Cl 2 with 1,4-diazine derivatives of o -phenanthroline [(N^N) = dipyrido[ a,c ]phenazine (dppz), dipyrido[ f,h ]quinoxaline (dpq)] were studied in comparison with those of the free diimine (N^N) ligands, dibenzo-substituted 1,4-diazines [dibenzo[ f,h ]quinoxaline (dbq), dibenzo[ a,c ]phenazine (dbpz)], and cyclometallated dichloride [Pd(C^N)(μ-Cl)] 2 and ethylenediamine [Pd(C^N)En]Cl complexes derived from dibenzo-substituted 1,4-diazines.

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Key concepts: Chemistry, Electrochemistry, Combinatorial chemistry, Computational chemistry, Medicinal chemistry, Physical chemistry, Electrode