1996Journal of Physics Condensed MatterRequires access

Superparamagnetism and the Mössbauer spectrum of goethite: a comment on a recent proposal by Coeyet al

Stephen Bocquet

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Abstract

The distinctive Mössbauer spectra of goethite cannot be explained on the basis of superparamagnetism. Consideration of superparamagnetic fluctuations in only the transverse components of the sublattice magnetization (`mode superparamagnetism', proposed by Coey et al ), or of possible interactions between superparamagnetic particles, does not alter this conclusion.

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The distinctive Mössbauer spectra of goethite cannot be explained on the basis of superparamagnetism. Consideration of superparamagnetic fluctuations in only the transverse components of the sublattice magnetization (`mode superparamagnetism', proposed by Coey et al ), or of possible interactions between superparamagnetic particles, does not alter this conclusion.

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Available abstract

The distinctive Mössbauer spectra of goethite cannot be explained on the basis of superparamagnetism. Consideration of superparamagnetic fluctuations in only the transverse components of the sublattice magnetization (`mode superparamagnetism', proposed by Coey et al ), or of possible interactions between superparamagnetic particles, does not alter this conclusion.

Key concepts: Superparamagnetism, Condensed matter physics, Mössbauer spectroscopy, Materials science, Goethite, Magnetization, Nuclear magnetic resonance, Nanotechnology

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