2013•Chemical CommunicationsRequires access

NIR-fluorescent coumarin-fused BODIPY dyes with large Stokes shifts

Andrei Y. Bochkov, Акчурин Игорь Олегович, O.A. Dyachenko, V. F. Traven

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Abstract

A series of novel non-symmetrical coumarin-fused BODIPY dyes were synthesised. Their absorption and emission properties are strongly influenced by substitution in the coumarin moiety. Diethylamino-substituted dyes showed near-IR emission with large Stokes shifts (up to 144 nm) and good fluorescence quantum yields.

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What this paper is about

A series of novel non-symmetrical coumarin-fused BODIPY dyes were synthesised. Their absorption and emission properties are strongly influenced by substitution in the coumarin moiety. Diethylamino-substituted dyes showed near-IR emission with large Stokes shifts (up to 144 nm) and good fluorescence quantum yields.

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Available abstract

A series of novel non-symmetrical coumarin-fused BODIPY dyes were synthesised. Their absorption and emission properties are strongly influenced by substitution in the coumarin moiety. Diethylamino-substituted dyes showed near-IR emission with large Stokes shifts (up to 144 nm) and good fluorescence quantum yields.

Key concepts: Coumarin, BODIPY, Fluorescence, Stokes shift, Photochemistry, Moiety, Absorption (acoustics), Chemistry

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