Formation and quenching kinetics of ArF
M. Rokni, J. H. Jacob, Joseph A. Mangano, R. Brochu
Abstract
M. Rokni, J. H. Jacob, Joseph A. Mangano, R. Brochu
Abstract
In this paper we report on the formation and quenching kinetics of ArF* (2Σ1/2). The ArF* is produced by irradiating mixtures of Ar and F2. The primary formation channel is via the recombination of Ar+ and Ar+2 with F−. Quenching of ArF* by F2 and Ar have been measured by analyzing the ArF* 2Σ1/2→2Σ1/2 fluorescence as a function of the F2 and Ar partial pressures. We have also measured the displacement of the Ar in ArF* by Kr and Xe to form KrF* and XeF*, respectively.
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In this paper we report on the formation and quenching kinetics of ArF* (2Σ1/2). The ArF* is produced by irradiating mixtures of Ar and F2. The primary formation channel is via the recombination of Ar+ and Ar+2 with F−. Quenching of ArF* by F2 and Ar have been measured by analyzing the ArF* 2Σ1/2→2Σ1/2 fluorescence as a function of the F2 and Ar partial pressures. We have also measured the displacement of the Ar in ArF* by Kr and Xe to form KrF* and XeF*, respectively.
Key concepts: Quenching (fluorescence), Kinetics, Chemistry, Fluorescence, Argon, Chemical kinetics, Recombination, Photochemistry