1999•The Journal of Chemical PhysicsRequires access

A many-particle treatment of the reversible reaction A+B⇔C+B

Irina V. Gopich, A.A. Kipriyanov, Alexander B. Doktorov

Open publisher page 44 citations

Abstract

A many-particle consideration of diffusion-influenced reversible pseudo-first order reaction A+B⇌C+B is presented. It is shown that the lowest order (in concentration) of the memory matrix is not sufficient for describing the binary kinetics of the reaction. Binary kinetic equations describing both stationary and nonstationary stages of the kinetics have been obtained using diagrammatic representation and selecting the necessary diagrams. Comparison with the fully renormalized kinetic theory is made by considering the contact approximation for reactivity.

About this research paper

What this paper is about

A many-particle consideration of diffusion-influenced reversible pseudo-first order reaction A+B⇌C+B is presented. It is shown that the lowest order (in concentration) of the memory matrix is not sufficient for describing the binary kinetics of the reaction. Binary kinetic equations describing both stationary and nonstationary stages of the kinetics have been obtained using diagrammatic representation and selecting the necessary diagrams. Comparison with the fully renormalized kinetic theory is made by considering the contact approximation for reactivity.

Why it matters

OpenAlex reports 44 citations for this work. Citation counts describe recorded attention and do not establish research quality.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

A many-particle consideration of diffusion-influenced reversible pseudo-first order reaction A+B⇌C+B is presented. It is shown that the lowest order (in concentration) of the memory matrix is not sufficient for describing the binary kinetics of the reaction. Binary kinetic equations describing both stationary and nonstationary stages of the kinetics have been obtained using diagrammatic representation and selecting the necessary diagrams. Comparison with the fully renormalized kinetic theory is made by considering the contact approximation for reactivity.

Key concepts: Binary number, Representation (politics), Kinetics, Thermodynamics, Particle (ecology), Diagrammatic reasoning, Kinetic energy, Statistical physics

Related papers

Back to paper searchBrowse research topicsOriginal source
A many-particle treatment of the reversible reaction A+B⇔C+B — Research Paper | ScholarLens