2003Chemistry LettersRequires access

Excellent Catalytic Performances of SBA-15-supported Vanadium Oxide for Partial Oxidation of Methane to Formaldehyde

Baomin Lin, Xiaoxing Wang, Qian Guo, Wei Yang, Qinghong Zhang, Ye Wang

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Abstract

Abstract Vanadium oxide supported on SBA-15 exhibits superior catalytic performances for the partial oxidation of methane to formaldehyde. A space-time yield of formaldehyde as high as 93 mol kgcat.−1h−1 has been obtained with a formaldehyde selectivity of 94% over 3 wt % VOx/SBA-15 catalyst, significantly higher than those reported so far.

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Abstract Vanadium oxide supported on SBA-15 exhibits superior catalytic performances for the partial oxidation of methane to formaldehyde. A space-time yield of formaldehyde as high as 93 mol kgcat.−1h−1 has been obtained with a formaldehyde selectivity of 94% over 3 wt % VOx/SBA-15 catalyst, significantly higher than those reported so far.

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Available abstract

Abstract Vanadium oxide supported on SBA-15 exhibits superior catalytic performances for the partial oxidation of methane to formaldehyde. A space-time yield of formaldehyde as high as 93 mol kgcat.−1h−1 has been obtained with a formaldehyde selectivity of 94% over 3 wt % VOx/SBA-15 catalyst, significantly higher than those reported so far.

Key concepts: Chemistry, Formaldehyde, Partial oxidation, Methane, Catalysis, Vanadium oxide, Vanadium, Oxide

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