Biodegradable extruded starch blends

Abstract We prepared biodegradable extruded starch blends by first mixing starch with additives and then processing the mixture in an extruder. The mechanical properties, including tensile strength and elongation at break, solubility, biodegradability, rheological properties, molecular weight, and glass‐transition temperature of the extruded blends were studied. Glycerol and urea, to some extent, could both decrease the tensile strength and increase the percentage elongation at break because the former acts as a plasticizer and the latter can break down interactions among starch macromolecules. The extruded starch blends showed thermoplasticity, and their melts behaved as pseudoplastic liquids at a comparatively low shear rate. The biodegradability of the extruded starch was slightly higher than that of native starch. The molecular weight of starch displayed a decreasing tendency after extruding modification. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 627–635, 2003