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2013•Journal of Natural ProductsRequires access

Chemoenzymatic Total Synthesis of the Phytotoxic Geranylcyclohexentriol (−)-Phomentrioloxin

Xinghua Ma, Martin G. Banwell, Anthony C. Willis

Open publisher page 30 citations

Abstract

The enantiomeric form, 1R, of the structure (1S) assigned to the phytotoxic natural product phomentrioloxin has been synthesized in seven steps from the homochiral cis-1,2-dihydrocatechol 3. These studies reveal that the true structure of phomentrioloxin is represented by 1R and not by 1S.

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What this paper is about

The enantiomeric form, 1R, of the structure (1S) assigned to the phytotoxic natural product phomentrioloxin has been synthesized in seven steps from the homochiral cis-1,2-dihydrocatechol 3. These studies reveal that the true structure of phomentrioloxin is represented by 1R and not by 1S.

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OpenAlex reports 30 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

The enantiomeric form, 1R, of the structure (1S) assigned to the phytotoxic natural product phomentrioloxin has been synthesized in seven steps from the homochiral cis-1,2-dihydrocatechol 3. These studies reveal that the true structure of phomentrioloxin is represented by 1R and not by 1S.

Key concepts: Enantiomer, Natural product, Stereochemistry, Total synthesis, Chemistry, Stereoisomerism, Chemical synthesis, Natural compound

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Chemoenzymatic Total Synthesis of the Phytotoxic Geranylcyclohexentriol (−)-Phomentrioloxin — Research Paper | ScholarLens