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1965•The Journal of Chemical PhysicsRequires access

Solid Solution of Argon and Krypton; Refined Measurements

B. E. F. Fender, G. D. Halsey

Open publisher page 17 citations

Abstract

Vapor pressures of argon—krypton mixtures at vanishingly small solid accumulation have been analyzed to give values of the interaction energy parameter wAB for a number of Ar–Kr solid solutions at temperatures between 85° and 101°K and in the argon mole-fraction range 4% to 18%. Vapor pressures and triple points of pure argon and krypton are also reported. The mole-fraction dependence of wAB is negligible, and compatible with that predicted by an exact form of the regular solution or Ising lattice problem.

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Vapor pressures of argon—krypton mixtures at vanishingly small solid accumulation have been analyzed to give values of the interaction energy parameter wAB for a number of Ar–Kr solid solutions at temperatures between 85° and 101°K and in the argon mole-fraction range 4% to 18%. Vapor pressures and triple points of pure argon and krypton are also reported. The mole-fraction dependence of wAB is negligible, and compatible with that predicted by an exact form of the regular solution or Ising lattice problem.

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Available abstract

Vapor pressures of argon—krypton mixtures at vanishingly small solid accumulation have been analyzed to give values of the interaction energy parameter wAB for a number of Ar–Kr solid solutions at temperatures between 85° and 101°K and in the argon mole-fraction range 4% to 18%. Vapor pressures and triple points of pure argon and krypton are also reported. The mole-fraction dependence of wAB is negligible, and compatible with that predicted by an exact form of the regular solution or Ising lattice problem.

Key concepts: Krypton, Argon, Mole fraction, Solid solution, Chemistry, Argon gas, Ising model, Analytical Chemistry (journal)

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