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1996•Acta Crystallographica Section C Crystal Structure CommunicationsRequires access

Trichloro[η5-(trimethylstannyl)cyclopentadienyl]titanium

Andrei V. Churakov, Ludmila G. Kuz'mina

Open publisher page 3 citations

Abstract

The title compound, [TiCl3{(CH3)3Sn(C5H4)}], is the first structurally characterized complex of an early transition metal with a cyclopentadienyl ligand-bearing stannyl moiety. The Ti—Cp distance of 1.986 (4) Å [where Cp is the centroid of the cyclopentadienyl (Cp) ring] is the shortest among the complexes containing the CpTiCl3 moiety.

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What this paper is about

The title compound, [TiCl3{(CH3)3Sn(C5H4)}], is the first structurally characterized complex of an early transition metal with a cyclopentadienyl ligand-bearing stannyl moiety. The Ti—Cp distance of 1.986 (4) Å [where Cp is the centroid of the cyclopentadienyl (Cp) ring] is the shortest among the complexes containing the CpTiCl3 moiety.

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Available abstract

The title compound, [TiCl3{(CH3)3Sn(C5H4)}], is the first structurally characterized complex of an early transition metal with a cyclopentadienyl ligand-bearing stannyl moiety. The Ti—Cp distance of 1.986 (4) Å [where Cp is the centroid of the cyclopentadienyl (Cp) ring] is the shortest among the complexes containing the CpTiCl3 moiety.

Key concepts: Cyclopentadienyl complex, Moiety, Chemistry, Ligand (biochemistry), Ring (chemistry), Stereochemistry, Titanium, Metal

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