2008•Russian Journal of Inorganic ChemistryRequires access

Crystal chemistry of lanthanide oxochlorotungstates

Н. Н. Лобанов, T. A. Kuznetsova

Abstract

Crystal chemical properties of lanthanide oxochlorotungstates of composition LnWO 4 Cl (Ln=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm) are reported. The unit cell parameters a, b, c, c′ , and V of the LnWO 4 Cl compounds are correlated with lanthanide ionic radii from different radius systems and with the lanthanide atomic number. The ionic radius systems most suitable for describing the crystal chemical properties of the lanthanide oxochlorotungstates are determined.

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Key concepts: Lanthanide, Ionic radius, Crystal chemistry, Lanthanide contraction, Ionic bonding, Crystallography, Crystal (programming language), Chemistry