2007•Russian Journal of Physical Chemistry ARequires access

The melting and boiling points of compounds in homologous series of monohalogenated n-alkanes

Mikhail F. Bolotnikov, Yu. A. Neruchev

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Abstract

The available data on the melting and boiling points in homologous series of normal 1-fluoro-, 1-chloro-, 1-bromo-, and 1-iodoalkanes were critically analyzed. A correlation was observed between the melting and boiling points of halogenated even and odd n -alkanes. This allowed us to obtain an interpolation equation for predicting compound melting points.

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What this paper is about

The available data on the melting and boiling points in homologous series of normal 1-fluoro-, 1-chloro-, 1-bromo-, and 1-iodoalkanes were critically analyzed. A correlation was observed between the melting and boiling points of halogenated even and odd n -alkanes. This allowed us to obtain an interpolation equation for predicting compound melting points.

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Available abstract

The available data on the melting and boiling points in homologous series of normal 1-fluoro-, 1-chloro-, 1-bromo-, and 1-iodoalkanes were critically analyzed. A correlation was observed between the melting and boiling points of halogenated even and odd n -alkanes. This allowed us to obtain an interpolation equation for predicting compound melting points.

Key concepts: Homologous series, Boiling point, Boiling, Chemistry, Series (stratigraphy), Melting point, Alkane, Thermodynamics

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