H. W. Geluk, Th. J. de Boer
Abstract
The 2,4,6,9- tetradehydroadamantane (pentacyclo[4,4,0,02,1003,5,04,8]decane)(III), formed by thermolysis of adamantane-2,6-diaone bis(tosylhydrazone)(II), gives upon catalytic hydrogenation tetracyclo[4,4,0,02,10,04,8]decane (VI) as the main product.
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The 2,4,6,9- tetradehydroadamantane (pentacyclo[4,4,0,02,1003,5,04,8]decane)(III), formed by thermolysis of adamantane-2,6-diaone bis(tosylhydrazone)(II), gives upon catalytic hydrogenation tetracyclo[4,4,0,02,10,04,8]decane (VI) as the main product.
Key concepts: Decane, Adamantane, Thermal decomposition, Chemistry, Decomposition, Catalysis, Medicinal chemistry, Organic chemistry