P. M. G. Bavin
Abstract
Methyl phenanthrene-9-carboxylate, dimethyl phenanthrene-9,10-dicarboxylate, and N,N-dimethyl phenanthrene-9-carboxaraide have been prepared directly from fluorene by a novel route. Neighboring group participation by carbomethoxy has been clearly demonstrated in the reactions of some 9,9-disubstituted fluorenes.
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Methyl phenanthrene-9-carboxylate, dimethyl phenanthrene-9,10-dicarboxylate, and N,N-dimethyl phenanthrene-9-carboxaraide have been prepared directly from fluorene by a novel route. Neighboring group participation by carbomethoxy has been clearly demonstrated in the reactions of some 9,9-disubstituted fluorenes.
Key concepts: Phenanthrene, Fluorene, Chemistry, Bifunctional, Carboxylate, Organic chemistry, Medicinal chemistry, Catalysis