Triplet Ps annihilation parameters in ethanol/ c i s -2-pentene/platinum mixtures containing platinum or platinum on charcoal
Judith L. Ciottone, F. Lander
Abstract
Judith L. Ciottone, F. Lander
Abstract
Positron lifetimes and intensities were compared, with and without external mixing, for simulated hydrogenation reaction mixtures consisting of 2/1, 1/1, 0.25/2, 0.5/2, 0.75/2, 1/2, and 1.5/2 ethanol/cis-2-pentene molar ratios to which 0.6 mg platinum powder or 5% platinum on charcoal were added. For platinum mixtures marked quenching of all o-Ps lifetimes and intensities occurred with external mixing. For 1/2 and 1.5/2 platinum-on-charcoal mixtures, the combined o-Ps intensity increased from 66% to 76% and from 30% to 76%, respectively, with external mixing.
OpenAlex reports 1 citations for this work. Citation counts describe recorded attention and do not establish research quality.
A contribution statement is not available in the OpenAlex record.
Method details are not available in the OpenAlex metadata.
Findings are not separately available in the OpenAlex metadata.
Limitations are not available in the OpenAlex metadata.
Application details are not available in the OpenAlex metadata.
Positron lifetimes and intensities were compared, with and without external mixing, for simulated hydrogenation reaction mixtures consisting of 2/1, 1/1, 0.25/2, 0.5/2, 0.75/2, 1/2, and 1.5/2 ethanol/cis-2-pentene molar ratios to which 0.6 mg platinum powder or 5% platinum on charcoal were added. For platinum mixtures marked quenching of all o-Ps lifetimes and intensities occurred with external mixing. For 1/2 and 1.5/2 platinum-on-charcoal mixtures, the combined o-Ps intensity increased from 66% to 76% and from 30% to 76%, respectively, with external mixing.
Key concepts: Platinum, Charcoal, Quenching (fluorescence), Annihilation, Chemistry, Mixing (physics), Pentene, Analytical Chemistry (journal)