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On the Use of the Kinetic Method for the Determination of Proton Affinities by Fourier-transform Ion Cyclotron Resonance Mass Spectrometry

M. Decouzon, Jean François Gal, Marta Herreros, Pierre‐Charles Maria, Jason Murrell, John F. J. Todd

Open publisher page 30 citations

Abstract

The use in Fourier-transform ion cyclotron resonance (FTICR) mass spectrometry of the collision-induced dissociation of proton-bound dimers, the kinetic method or Cooks's method, is tested. This method is compared with the proton-transfer equilibrium method. Good agreement between the two methods is observed. Advantages and limitations of the FTICR kinetic method are briefly discussed.

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What this paper is about

The use in Fourier-transform ion cyclotron resonance (FTICR) mass spectrometry of the collision-induced dissociation of proton-bound dimers, the kinetic method or Cooks's method, is tested. This method is compared with the proton-transfer equilibrium method. Good agreement between the two methods is observed. Advantages and limitations of the FTICR kinetic method are briefly discussed.

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Available abstract

The use in Fourier-transform ion cyclotron resonance (FTICR) mass spectrometry of the collision-induced dissociation of proton-bound dimers, the kinetic method or Cooks's method, is tested. This method is compared with the proton-transfer equilibrium method. Good agreement between the two methods is observed. Advantages and limitations of the FTICR kinetic method are briefly discussed.

Key concepts: Fourier transform ion cyclotron resonance, Chemistry, Ion cyclotron resonance, Mass spectrometry, Kinetic energy, Affinities, Selected ion monitoring, Fourier transform

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