1979•Bulletin of the Chemical Society of JapanOpen access

Absorption and Circular Dichroism Spectra of Bis(ethylenediamine)(1,3-diamine)cobalt(III) Complexes

Kazuo Kashiwabara, Masaaki Kojima, Sumio Arakawa, Junnosuke Fujita

Abstract

Abstract New bis(ethylenediamine)cobalt(III) complexes containing various 1,3-diamines have been prepared and resolved (or separated) into optical isomers. The preferred conformations of six-membered 1,3-diamine chelate rings in these complexes seem to be reflected on the absorption and circular dichroism spectra.

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Key concepts: Ethylenediamine, Chemistry, Diamine, Cobalt, Circular dichroism, Absorption (acoustics), Chelation, Absorption spectroscopy