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2014•Russian Journal of General ChemistryRequires access

Reaction of secondary phosphine chalcogenides with diallylamine

S. I. Verkhoturova, T. I. Kazantseva, S. N. Arbuzova, Alexander I. Albanov, Nina K. Gusarova, Boris Aleksandrovich Trofimov

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Abstract

Diphenyl- or bis(2-phenylethyl)phosphine sulfides and -phosphine selenides react with diallylamine under radical initiation (UV or AIBN) to afford the corresponding diadducts and tetrahydropyrrolylmethyl phosphine chalcogenides. The yield and the ratio of the products depend on the structure of the starting secondary phosphine chalcogenides.

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What this paper is about

Diphenyl- or bis(2-phenylethyl)phosphine sulfides and -phosphine selenides react with diallylamine under radical initiation (UV or AIBN) to afford the corresponding diadducts and tetrahydropyrrolylmethyl phosphine chalcogenides. The yield and the ratio of the products depend on the structure of the starting secondary phosphine chalcogenides.

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Available abstract

Diphenyl- or bis(2-phenylethyl)phosphine sulfides and -phosphine selenides react with diallylamine under radical initiation (UV or AIBN) to afford the corresponding diadducts and tetrahydropyrrolylmethyl phosphine chalcogenides. The yield and the ratio of the products depend on the structure of the starting secondary phosphine chalcogenides.

Key concepts: Phosphine, Chemistry, Yield (engineering), Organic chemistry, Metallurgy, Catalysis, Materials science

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