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2008•OrganometallicsRequires access

A Thermally Switchable Latent Ruthenium Olefin Metathesis Catalyst

A. Ben-Asuly, Eyal Tzur, Charles E. Diesendruck, M. V. SIGALOV, Israel Goldberg, N. Gabriel Lemcoff

Open publisher page 153 citations

Abstract

The synthesis and characterization of a cis -dichloro sulfur chelated olefin metathesis catalyst is presented. The catalyst was extremely stable at room temperature in solution under ambient conditions and was shown to exhibit a thermo-switchable behavior for ring-closing olefin metathesis of diethyl diallylmalonate, being active at 80 °C and inactive at room temperature.

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What this paper is about

The synthesis and characterization of a cis -dichloro sulfur chelated olefin metathesis catalyst is presented. The catalyst was extremely stable at room temperature in solution under ambient conditions and was shown to exhibit a thermo-switchable behavior for ring-closing olefin metathesis of diethyl diallylmalonate, being active at 80 °C and inactive at room temperature.

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OpenAlex reports 153 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

The synthesis and characterization of a cis -dichloro sulfur chelated olefin metathesis catalyst is presented. The catalyst was extremely stable at room temperature in solution under ambient conditions and was shown to exhibit a thermo-switchable behavior for ring-closing olefin metathesis of diethyl diallylmalonate, being active at 80 °C and inactive at room temperature.

Key concepts: Chemistry, Olefin metathesis, Catalysis, Ruthenium, Ring-opening metathesis polymerisation, Acyclic diene metathesis, Metathesis, Olefin fiber

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