Electron‐impact studies XCII–Negative ion‐molecule reactions in anhydride systems. Perfluoroacetic anhydride with succinic, maleic and phthalic anhydrides. An ion cyclotron resonance study
John H. Bowie, B. D. Williams
Abstract
John H. Bowie, B. D. Williams
Abstract
Abstract The trifluoroacetate anion undergoes reaction with succinic, maleic and phthalic anhydrides to yield 1 : 1 adducts. The molecular anions of maleic and phthalic anhydride also undergo reaction with perfluoroacetic anhydride to produce [CF3CO2]−· Maleic anhydride parent ions produce [M + CF3CO·]− ions when allowed to react with perfluoroacetic anhydride.
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Abstract The trifluoroacetate anion undergoes reaction with succinic, maleic and phthalic anhydrides to yield 1 : 1 adducts. The molecular anions of maleic and phthalic anhydride also undergo reaction with perfluoroacetic anhydride to produce [CF3CO2]−· Maleic anhydride parent ions produce [M + CF3CO·]− ions when allowed to react with perfluoroacetic anhydride.
Key concepts: Phthalic anhydride, Succinic anhydride, Maleic anhydride, Chemistry, Ion, Polymer chemistry, Organic chemistry, Yield (engineering)