Syntheses of Anolignans A and B Using Ruthenium-Catalyzed Cross-Enyne Metathesis
Miwako Mori, Keisuke Tonogaki, Nao Nishiguchi
Abstract
Miwako Mori, Keisuke Tonogaki, Nao Nishiguchi
Abstract
Anolignans A and B were synthesized using ruthenium-catalyzed cross-enyne metathesis as the key steps. The 1,3-diene moieties of these natural products were constructed by the introduction of the methylene parts of ethylene into alkyne using Grubbs' catalyst.
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Anolignans A and B were synthesized using ruthenium-catalyzed cross-enyne metathesis as the key steps. The 1,3-diene moieties of these natural products were constructed by the introduction of the methylene parts of ethylene into alkyne using Grubbs' catalyst.
Key concepts: Enyne metathesis, Ruthenium, Chemistry, Enyne, Metathesis, Catalysis, Alkyne, Ethylene