Lindblad approach to quantum dynamics of open systems

A Lindblad approach is presented to describe quantum dynamics of open systems. It is based on a construction of a Lindblad functional from the microscopic Caldeira-Leggett model for linear dissipation. It leads to a master equation for the reduced density matrix, which preserves positive evolution on short times and asymptotically approaches equilibrium at high and low temperatures. This master equation is applied to study the femtosecond dynamics of vibrational heating, relaxation, and bond breaking at a metal surface. Both a direct solution of the density matrix and an indirect solution with stochastic wave functions are presented. The latter, besides its statistical equivalence to the density matrix, provides a more physical picture about quantum jumps of individual open systems.