Novel Microporous Metal–Organic Framework Exhibiting High Acetylene and Methane Storage Capacities
Xing Duan, Chuan‐De Wu, Shengchang Xiang, Wei Zhou, Taner Yildirim, Yuanjing Cui, Yu Yang, Banglin Chen, Guodong Qian
Abstract
Xing Duan, Chuan‐De Wu, Shengchang Xiang, Wei Zhou, Taner Yildirim, Yuanjing Cui, Yu Yang, Banglin Chen, Guodong Qian
Abstract
A new organic hexacarboxylic acid, 5,5',5″-(9H-carbazole-3,6,9-triyl)triisophthalic acid (H6CTIA), was developed to construct its first microporous metal-organic framework (MOF), Cu6(CTIA)2 (ZJU-70). With open metal sites and suitable pore sizes, this MOF exhibits high acetylene and methane storage capacities at room temperature.
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A new organic hexacarboxylic acid, 5,5',5″-(9H-carbazole-3,6,9-triyl)triisophthalic acid (H6CTIA), was developed to construct its first microporous metal-organic framework (MOF), Cu6(CTIA)2 (ZJU-70). With open metal sites and suitable pore sizes, this MOF exhibits high acetylene and methane storage capacities at room temperature.
Key concepts: Chemistry, Microporous material, Acetylene, Methane, Metal-organic framework, Chemical engineering, Inorganic chemistry, Organic chemistry