1991•Journal of the Physical Society of JapanRequires access

Multiplet Splitting in Ni 2 p X-Ray Photoemission Spectra of Ni Dihalides

Kozo Okada, Akio Kotani

Abstract

A cluster model approach is applied to the analysis of the Ni 2 p core-level X-ray photoemission spectra (XPS) in Ni dihalides, where the intraatomic multiplet coupling is fully taken into account. The difference in the line shape between the 2 p 3/2 and 2 p 1/2 spectra is shown to originate from the multiplet splitting of their charge transfer satellites.

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Key concepts: Multiplet, Spectral line, Physics, Atomic physics, X-ray photoelectron spectroscopy, Cluster (spacecraft), Coupling (piping), Inverse photoemission spectroscopy