1993Journal of the American Oil Chemists SocietyRequires access

Solubilization behavior ofn‐octane andn‐octanol in polyoxyethylated nonionic micelles

Yoshihiro Saito, Masahiko Abe, Takatoshi Sato

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Abstract

The solubilization ofn‐octane andn‐octanol in nonionic micelles was investigated by means of various techniques including solubilization, fluorescence and dynamic light‐scattering measurements. With respect to the effect of oxyethylene chainlength of the surfactants, different solubilization behavior was observed betweenn‐octane andn‐octanoli.e., the solubilization ofn‐octane decreases with an increase in oxyethylene chainlength, while that ofn‐octanol increases. This solubilization behavior is explained from the standpoint of the volume of hydrophobic and hydrophilic regions in a micelle.

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What this paper is about

The solubilization ofn‐octane andn‐octanol in nonionic micelles was investigated by means of various techniques including solubilization, fluorescence and dynamic light‐scattering measurements. With respect to the effect of oxyethylene chainlength of the surfactants, different solubilization behavior was observed betweenn‐octane andn‐octanoli.e., the solubilization ofn‐octane decreases with an increase in oxyethylene chainlength, while that ofn‐octanol increases. This solubilization behavior is explained from the standpoint of the volume of hydrophobic and hydrophilic regions in a micelle.

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Available abstract

The solubilization ofn‐octane andn‐octanol in nonionic micelles was investigated by means of various techniques including solubilization, fluorescence and dynamic light‐scattering measurements. With respect to the effect of oxyethylene chainlength of the surfactants, different solubilization behavior was observed betweenn‐octane andn‐octanoli.e., the solubilization ofn‐octane decreases with an increase in oxyethylene chainlength, while that ofn‐octanol increases. This solubilization behavior is explained from the standpoint of the volume of hydrophobic and hydrophilic regions in a micelle.

Key concepts: Solubilization, Octane, Micelle, Octanol, Chemistry, Organic chemistry, Partition coefficient, Aqueous solution

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