2003Physics of the Solid StateRequires access

Grain-boundary diffusion in nanocrystals with a time-dependent diffusion coefficient

А. А. Назаров

Open publisher page 26 citations

Abstract

A solution to the equation of grain-boundary diffusion is obtained under conditions where migration of the diffusant from the boundaries into the grains is absent and the diffusion coefficient decreases with time from an increased value to a value characteristic of equilibrium grain boundaries. The specific features of the grain-boundary diffusion in nanocrystals are qualitatively analyzed in terms of this solution.

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What this paper is about

A solution to the equation of grain-boundary diffusion is obtained under conditions where migration of the diffusant from the boundaries into the grains is absent and the diffusion coefficient decreases with time from an increased value to a value characteristic of equilibrium grain boundaries. The specific features of the grain-boundary diffusion in nanocrystals are qualitatively analyzed in terms of this solution.

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Available abstract

A solution to the equation of grain-boundary diffusion is obtained under conditions where migration of the diffusant from the boundaries into the grains is absent and the diffusion coefficient decreases with time from an increased value to a value characteristic of equilibrium grain boundaries. The specific features of the grain-boundary diffusion in nanocrystals are qualitatively analyzed in terms of this solution.

Key concepts: Grain boundary diffusion coefficient, Effective diffusion coefficient, Grain boundary, Materials science, Diffusion, Nanocrystal, Condensed matter physics, Thermodynamics

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