2002•New Journal of ChemistryRequires access

Pb(dca) 2 (dca = dicyanamide): a novel 3D compound with unusual coordination modes of dicyanamide

Yujun Shi, Xue-Tai Chen, Yi‐Zhi Li, Zi‐Ling Xue, Xiao‐Zeng You

Abstract

The crystal structure determination of Pb(dca)2 reveals a new M(dca)2 structural type with two unusual coordination modes of dicyanamide existing in a novel (4,5,9)-connected 3D-polymeric structure, indicating the versatile coordination behaviour of both dicyanamide and lead atom.

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Key concepts: Dicyanamide, Chemistry, Crystal structure, Crystallography, Stereochemistry, Organic chemistry, Catalysis, Ionic liquid