1995•Journal of the Chemical Society Perkin Transactions 1Requires access

Synthesis of imidazole 1-oxides from 1,2-diimines

Jesús Alcázar, Mikael Begtrup, Antonio de la Hoz

Abstract

Various 3-substituted imidazole 1-oxides have been prepared by reaction of a 1,2-dicarbonyl compound mono- or di-imine with an oxime. The structure of the oxime determines the imidazole C-2 substituent whilst the structure of the mono- or di-imine determines the substitution patterns at N-3, C-4 and C-5.

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Key concepts: Imidazole, Oxime, Imine, Chemistry, Substituent, Medicinal chemistry, Stereochemistry, Organic chemistry