1987•Bulletin des Sociétés Chimiques BelgesRequires access

I‐Isocyanoaromadendrane, A New Isonitrile Sesquiterpene from the Sponge Acanthella Acuta

J. C. Braekman, D. Daloze, F. Deneubourg, J. Huysecom, G. Vandevyver

Abstract

Abstract Two isonitrile sesquiterpenes 2 and 3 have been isolated from the toxic dichloromethane extract of the marine sponge Acanthella acuta. Compound 2 was found to be identical with axisonitrile‐3. compound 3, 1‐isocyanoaromadendrane, is a novel sesquiterpene whose structure has been determined on the basis of its spectral properties and by chemical correlation with palustrol.

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Key concepts: Sesquiterpene, Sponge, Dichloromethane, Stereochemistry, Chemistry, Spectral analysis, Organic chemistry, Botany