Thermodynamic requirements for maximum internal combustion engine cycle efficiency. Part 1: Optimal combustion strategy

This is the first of a two-part study that examines, from the exergy management standpoint, the fundamental thermodynamic requirements for maximizing internal combustion (IC) engine cycle efficiency. The optimal cycle is shown to comprise three distinct engine architectural elements — reactant preparation, combustion, and work extraction from the products — each of which can be analysed separately. This study shows, based on dynamical system optimization, that it is the equilibrium thermodynamics (specifically, the constant-internal energy—volume ( UV) product state at the end of combustion) and not chemical kinetics (i.e. reactions taking place during combustion) that ultimately dictates the amount of exergy destroyed due to combustion. The strategy for minimizing this destruction term reduces to carrying out reactions at the highest possible internal energy state — following what may be called the ‘extreme state’ principle — so as to minimize the corresponding constant- UV entropy change from reactants to equilibrium products. The extreme state principle remains unaltered when system inhomogeneity (from fuel vaporization and mixing with air) and heat loss are accounted for. Based on this optimal combustion strategy, the companion paper examines the remaining elements of the engine cycle (reactant preparation and work extraction) so as to improve overall cycle efficiency.